If you watch the season 3 episode, "Mask of the Wolf" it looks Navy blue in the beginning but later it looks black. I think this might be the same one he wears in the fith season because it does look more close fitting and less puffy compared to the one in the sixth and seventh season. I too have always noticed this subtle difference and it drove me nuts trying to figure it out! Compare the fith and Seventh season Jackets here: Notice the change in cut. 
"...Verily, Verily, I say unto thee, Except a man be born again, he cannot see the kingdom of God." John 3:3
"And where are my shoelaces!?"-Dexter Fillmore, Deep Cover
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